SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [(SALPANAL)LI(THF)(2)](2) AND [(SALOMPHANAL)-LI(THF)(2)](2) - A NEW CLASS OF ALUMINUM ANION

被引：22

作者：

ATWOOD, DA

RUTHERFORD, D

机构：

[1] Department of Chemistry, North Dakota State University, Fargo

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 15期

关键词：

D O I：

10.1021/ic00119a026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(SalpanAl)Li(THF)(2)](2) (1) and [(SalomphanAl)Li(THF)(2)](2) (2) are two members of a new class of aluminum anion with metal-ligand stoichiometries of 1:1. Both compounds were spectroscopically and structurally characterized. In 1 (shown) the dihedral angles for the two AlLiO2 planes with respect to the central Al2N2 plane are +50.0 degrees (for Al(1) and -53.2 degrees (for Al(2)). This ''twist'' gives the molecule helical chirality.

引用

页码：4008 / 4010

页数：3

共 31 条

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[2] IMMORTAL POLYMERIZATION - POLYMERIZATION OF EPOXIDE CATALYZED BY AN ALUMINUM PORPHYRIN ALCOHOL SYSTEM [J].