THE CONVERSION OF METHANOL INTO HYDROCARBONS OVER DODECATUNGSTOPHOSPHORIC ACID

被引：43

作者：

BABA, T ^{[1
]}

SAKAI, J ^{[1
]}

WATANABE, H ^{[1
]}

ONO, Y ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM ENGN,MEGURO KU,TOKYO 152,JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1982年 / 55卷 / 08期

关键词：

D O I：

10.1246/bcsj.55.2555

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

DODECATUNGSTOPHOSPHORIC ACID (TPA) IS A VERY EFFECTIVE CATALYST FOR THE CONVERSION OF METHANOL INTO HYDROCARBONS. THE EFFECTS OF THE REACTION PARAMETERS, SUCH AS THE TEMPERATURE OR THE METHANOL PARTIAL PRESSURE, WERE THEREFORE EXAMINED. THE KINETIC FEATURES OF THE CONVERSION OVER TPA ARE QUITE DIFFERENT FROM THOSE OVER ZSM-5 ZEOLITES. THIS DIFFERENCE IS CAUSED BY THE UNIQUE NATURE OF THE CONVERSION OVER TPA; METHANOL MOLECULES ARE SORBED AND UNDERGO THE CONVERSION IN THE BULK OF SOLID TPA.

引用

页码：2555 / 2559

页数：5

共 14 条

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