RUTHENIUM CATALYZED HYDROFORMYLATION REACTIONS USING IN SITU GENERATION OF SYNTHESIS GAS FROM AQUEOUS METHYL FORMATE

被引：13

作者：

JENNER, G

机构：

[1] Univ Louis Pasteur, Strasbourg, France

来源：

APPLIED CATALYSIS | 1991年 / 75卷 / 02期

关键词：

ALKENE HYDROFORMYLATION; METHYL FORMATE; RUTHENIUM; SYNGAS GENERATION;

D O I：

10.1016/S0166-9834(00)83138-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Aqueous methyl formate can be used as a source of carbon monoxide and hydrogen via catalysis with Ru3(CO)12+tricyclohexylphosphine in the hydroformylation of cycloalkenes and linear alkenes. Hydrogenation of the alkene is a competing reaction. The best results regarding formation of higher alcohols are obtained with lower alkenes. In some cases, the addition of Pd(acac)2 is able to modulate the selectivity with respect to the alcohols. The hydroformylation reaction involves [HRu3(CO)11]-.

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页码：289 / 298

页数：10

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