HIGH-PRESSURE ORGANIC-CHEMISTRY .17. DIELS-ALDER REACTION OF METHYL PALUSTRATE WITH MALEIC-ANHYDRIDE AND N-PHENYLMALEIMIDE

被引：7

作者：

KOTSUKI, H

KATAOKA, M

MATSUO, K

SUETOMO, S

SHIRO, M

NISHIZAWA, H

机构：

[1] ARAKAWA CHEM IND LTD,TSURUMI KU,OSAKA 538,JAPAN

[2] RIGAKU CORP,TOKYO 196,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 22期

关键词：

D O I：

10.1039/p19930002773

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diels-Alder reactions of methyl palustrate with a variety of dienophiles have been investigated under high pressure conditions. Thus, on reaction with maleic anhydride the adducts 5 (19%) and 6 (8%) are produced and with N-phenylmaleimide compound 7 (68%) is obtained. The structures and relative stereochemistry of these unprecedented adducts, 5 and 7, are established on the basis of spectral analysis (mainly 2D NMR) and X-ray diffraction.

引用

页码：2773 / 2776

页数：4

共 26 条

[1] IRREVERSIBLE ENZYME INHIBITORS .152. PROTEOLYTIC ENZYMES .X. INHIBITION OF GUINEA PIG COMPLEMENT BY SUBSTITUTED BENZAMIDINES [J].