DIMERIC BIS(TRIALKYLPHOSPHANE)RHODIUM CHLORIDES - PREPARATION AND CHARACTERIZATION

被引：51

作者：

BINGER, P

HAAS, J

GLASER, G

GODDARD, R

KRUGER, C

机构：

来源：

CHEMISCHE BERICHTE | 1994年 / 127卷 / 10期

关键词：

RHODIUM(I) COMPLEXES; TRIALKYLPHOSPHANE COMPLEXES; DIMERIZATION EQUILIBRIUM;

D O I：

10.1002/cber.19941271017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High-yield methods for the preparation of (PMe3)3RhCl (2) and [(R3P)2RhCl]2 [R = Me (3a); iPr (3b), and cyclohexyl (3c)] are described. The dimeric nature of 3b in the solid state has been established by an X-ray analysis.

引用

页码：1927 / 1929

页数：3

共 35 条

[1] BENN R, MAX PLANCK I KOHLENF
[2] BINGER P, 1990, MULTIPLE BONDS LOW C, P90
[3] BOEYENS JCA, 1986, S AFR J CHEM, V39, P229
[4] DINUCLEAR-BRIDGED D8 METAL-COMPLEXES .4. CRYSTAL AND MOLECULAR-STRUCTURE OF [RHCL(CO)(P(CH3)2C6H5)]2 AND ISOMERIZATION IN SOLUTION OF [RHCL(CO)(PR3)]2 COMPLEXES
BONNET, JJ
JEANNIN, Y
KALCK, P
MAISONNAT, A
POILBLANC, R
[J]. INORGANIC CHEMISTRY, 1975, 14 (04) : 743 - 747
[5] SIDE-ON BONDED DINITROGEN AND DIOXYGEN COMPLEXES OF RHODIUM(I) - SYNTHESIS AND CRYSTAL-STRUCTURES OF TRANS-CHLORO(DINITROGEN)-BIS(TRI-ISOPROPLPHOSPHINE)RHODIUM(I), CHLORO(DIOXYGEN)-BIS(TRI-ISOPROPLPHOSPHINE)RHODIUM(I), AND CHLORO(ETHYLENE)-BIS(TRI-ISOPROPYLPHOSPHINE)RHODIUM(I)
BUSETTO, C
DALFONSO, A
MASPERO, F
PEREGO, G
ZAZZETTA, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (19): : 1828 - &
[6] TRANSITION-METAL-CATALYZED CYCLIZATION OF ALKYNOIC ACIDS TO ALKYLIDENE LACTONES
CHAN, DMT
MARDER, TB
MILSTEIN, D
TAYLOR, NJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (21) : 6385 - 6388
[7] Cramer R., 1974, INORG SYNTH, V15, P14, DOI DOI 10.1002/9780470132463.CH4
[8] COORDINATION OF HIGHLY SUBSTITUTED ALKENES TO TRANSITION-METAL COMPLEXES - PREPARATION AND CRYSTAL AND MOLECULAR-STRUCTURES OF THE COMPLEXES [(RHCL(PH2PO2CCH=CME2))2] AND [(RHCL(PH2PO2CCH=CHCH=CHME))2]
CUPERTINO, DC
COLEHAMILTON, DJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (02): : 443 - 449
[9] CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE DIMER ETHYL ACETATE
CURTIS, MD
BUTLER, WM
GREENE, J
[J]. INORGANIC CHEMISTRY, 1978, 17 (10) : 2928 - 2931
[10] STRUCTURE OF AND METAL-METAL BONDING IN RH(CO)2CL
DAHL, LF
MARTELL, C
WAMPLER, DL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (07) : 1761 - &

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