Improved preparation of anhydrous lanthanide chlorides under mild conditions

被引：21

作者：

DellAmico, DB

Calderazzo, F

dellaPorta, C

Merigo, A

Biagini, P

Lugli, G

Wagner, T

机构：

[1] IGD ENICHEM,IST GUIDO DONEGANI SPA,I-28100 NOVARA,ITALY

[2] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,D-52074 AACHEN,GERMANY

来源：

INORGANICA CHIMICA ACTA | 1995年 / 240卷 / 1-2期

关键词：

lanthanide complexes; chloride complexes;

D O I：

10.1016/0020-1693(95)04568-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxides or carbonates of lanthanides (Ln) are converted under mild conditions into the corresponding solvated anhydrous chlorides LnCl(3)(ether)(n) by hydrogen chloride produced in situ from thionyl chloride and water in the presence of 1,2-dimethoxyethane under mild conditions.

引用

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页码：1 / 3

页数：3

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