INTRAMOLECULAR INSERTION OF ARYLCARBENES INTO C-SI BONDS

被引：8

作者：

KIRMSE, W

KONRAD, W

机构：

[1] Fakultät Für Chemie Der Ruhr-Universität, Bochum, D-4630

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 06期

关键词：

D O I：

10.1002/anie.199006611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CSi bonds are generally inert towards the intermolecular attack of carbenes. In contrast, arylcarbenes of type 1 exhibit intramolecular insertion into CSi bonds of the ortho side chain (for route b:Ph > Me, benzyl). (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：661 / 662

页数：2

共 17 条

[1]

BALDWIN JE, 1970, J CHEM SOC CHEM COMM, P576

[2]

Bassindale A. R., 1989, CHEM ORGANIC SILIC 2, P893

[3]

CORRIU RJP, 1989, CHEM ORGANIC SILICON, P1241

[4]

Creary X., 1986, ORG SYNTH, V64, P207, DOI DOI 10.1021/J001285A059