QUASI-EQUILIBRIUM RATE CONSTANTS FOR THERMIONIC EMISSION FROM SMALL PARTICLES

被引：122

作者：

KLOTS, CE

机构：

[1] Chemical Physics Section, Health and Safety Research Division, Oak Ridge National Laboratory, Oak Ridge

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 186卷 / 01期

关键词：

D O I：

10.1016/0009-2614(91)80194-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A modified hard-sphere model for electron capture by small aggregates is used to derive an expression for the rate constants for thermionic emission from isolated aggregates of matter. Its connection with earlier models for autoionization is indicated. The use of generalized Arrhenius plots for comparing experiment and theory is outlined.

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页码：73 / 76

页数：4

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