ZINC-CHLORIDE CATALYZED SILYLATION OF ALCOHOLS AND PHENOLS BY HEXAMETHYLDISILAZANE - A HIGHLY CHEMOSELECTIVE REACTION

被引：101

作者：

FIROUZABADI, H

KARIMI, B

机构：

[1] Chemistry Department College of Sciences, Shiraz University, Shiraz

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 12期

关键词：

D O I：

10.1080/00397919308011260

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hexamethyldisilazane (HMDS) in presence of a catalytic amount of anhydrous zinc chloride silylates efficiently and selectively different types of alcohols and phenols in refluxing acetonitrile or benzene-acetonitrile. This reagent in presence of anhydrous zinc chloride discriminates absolutely amines and thiols from alcohols.

引用

页码：1633 / 1641

页数：9

共 17 条

[1]

BIRKOFER L, 1975, J ORGANOMET CHEM, pC35

[2] CATALYSTS FOR SILYLATIONS WITH 1,1,1,3,3,3-HEXAMETHYLDISILAZANE [J].