THE CATALYTIC PINACOL REARRANGEMENT OF 1,2-DIOLS USING AN ANTIMONY(V) SALT

被引：27

作者：

HARADA, T

MUKAIYAMA, T

机构：

来源：

CHEMISTRY LETTERS | 1992年 / 01期

关键词：

D O I：

10.1246/cl.1992.81

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a catalytic amount of antimony(V) chloride or antimony(V) salt generated from antimony(V) chloride and silver hexafluoroantimonate, the pinacol rearrangement of several 1,2 - diols or their trimethylsilyl ethers proceeds smoothly to give the corresponding ketones in good yields.

引用

页码：81 / 84

页数：4

共 11 条

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[8] THE CATALYTIC FRIEDEL-CRAFTS ACYLATION REACTION USING A CATALYST GENERATED FROM GACL3 AND A SILVER SALT
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[J]. CHEMISTRY LETTERS, 1991, (06) : 1059 - 1062
[9] REDUCTIVE COUPLING OF CARBONYL-COMPOUNDS TO PINACOLS AND OLEFINS BY USING TICL4 AND ZN
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[10] THE EVALUATION OF CATALYSTS GENERATED FROM LEWIS-ACIDS AND SILVER PERCHLORATE IN A HIGHLY STEREOSELECTIVE GLYCOSYLATION OF 1-O-ACETYL-D-GLUCOSE
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KATSURADA, M
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[J]. CHEMISTRY LETTERS, 1991, (06) : 985 - 988

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