LOW-TEMPERATURE CRYSTAL AND MOLECULAR-STRUCTURE OF NITROBENZENE

被引：81

作者：

BOESE, R ^{[1
]}

BLASER, D ^{[1
]}

NUSSBAUMER, M ^{[1
]}

KRYGOWSKI, TM ^{[1
]}

机构：

[1] UNIV WARSAW,DEPT CHEM,PL-02093 WARSAW,POLAND

来源：

STRUCTURAL CHEMISTRY | 1992年 / 3卷 / 05期

关键词：

D O I：

10.1007/BF00678559

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal and molecular structure of nitrobenzene was determined at 103 K by X-ray diffraction, yielding R = 0.034 and a highly precise geometry of the molecule (esds of bond lengths less-than-or-equal-to 0.001 angstrom and bond angles less-than-or-equal-to 0.1-degrees). The bond angles in the ring agree very well with additive scheme based on angular substituent parameters. X-X electron density maps support the view that the C-N bond does not exhibit pi-character, and, hence, the nitro group interacts with the ring mostly by inductive effects.

引用

页码：363 / 368

页数：6

共 20 条

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