FERROCENYLSELENO AMINO-ALCOHOLS AS NEW CATALYSTS FOR THE HIGHLY ENANTIOSELECTIVE ALKYLATION OF ALDEHYDES

被引：32

作者：

FUKUZAWA, S

TSUDZUKI, K

机构：

[1] Department of Applied Chemistry, Chuo University, Bunkyo-ku, Tokyo

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 05期

关键词：

D O I：

10.1016/0957-4166(95)00119-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A chiral or a diastereomeric mixture of 1-[1-(N'N-dimethylaminoethyl)-2-(2'-hydroxyalkylseleno)]-ferrocene (DASF) was easily prepared by the chiral diferrocenyldiselenide (1)and:epoxides. DASF derivatives efficiently catalyzed the ethylation of aldehydes with diethyl zinc to give the secondary alcohols in good to excellent yield with up to 99 % ee.

引用

页码：1039 / 1042

页数：4

共 6 条

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