PHOSPHORUS-NITROGEN COMPOUNDS .65. THE REACTIONS OF HEXACHLOROCYCLOTRI-PHOSPHAZATRIENE WITH DIETHYL BIS-(HYDROXYMETHYL)MALONATE - COMPARISON OF PRODUCT TYPE AND OF THE P-31, H-1 AND C-13 NUCLEAR-MAGNETIC-RESONANCE SPECTRA WITH THE SPIRO DERIVATIVES OF PROPANE-1,3-DIOL AND 2,2-DIMETHYLPROPANE-1,3-DIOL

被引：5

作者：

ALKUBAISI, AH ^{[1
]}

SHAW, RA ^{[1
]}

机构：

[1] UNIV LONDON,BIRKBECK COLL,DEPT CHEM,GORDON HOUSE,29 GORDON SQ,LONDON WC1H 0PP,ENGLAND

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1991年 / 55卷 / 1-4期

关键词：

HEXACHLOROCYCLOTRIPHOSPHAZATRIENE; DIETHYL BIS(HYDROXYMETHYL)MALONATE; SPIRO COMPOUNDS; NMR STUDIES;

D O I：

10.1080/10426509108045921

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of hexachlorocyclotriphosphazatriene with diethyl bis(hydroxymethyl)malonate give the following spiro derivatives: mono, N3P3Cl4[(OCH2)2C(CO2Et)2], bis, N3P3Cl2[(OCH2)2C(CO2Et)2]2 and tris, N3P3[(OCH2)2C(CO2Et)2]3. A comparison is made of the products obtained by the above diol with those from propane-1, 3-diol and 2, 2-dimethylpropane-l, 3-diol. The 31P, 1H and 13C n. m.r. spectra of the spiro derivatives of the above three diols are compared. © 1991, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：49 / 57

页数：9

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