STEREOSELECTIVE REDUCTION OF GEM-DICHLOROCYCLOPROPANES TO CIS-MONOCHLOROCYCLOPROPANES BY LITHIUM ALUMINUM-HYDRIDE IN THE PRESENCE OF TITANIUM AND ZIRCONIUM COMPLEXES

被引：2

作者：

DZHEMILEV, UM

GAISIN, RL

TURCHIN, AA

TOLSTIKOV, GA

机构：

[1] Institute of Chemistry, Bashkir Science Center, Urals Branch, Academy of Sciences of the USSR, Ufa

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 09期

关键词：

D O I：

10.1007/BF00960415

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A versatile stereoselective method is presented for the synthesis of cis-monochlorocyclopropanes by the reduction of dehalogenated alkyl- and aryl-gem-dichlorocyclopropanes in the presence of catalytic quantities of titanium and zirconium complexes.

引用

页码：1845 / 1848

页数：4

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[2]

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[3]

DZHEMILEV UM, 1990, IAN SSSR KH, P1080

[4] STEREOCHEMISTRY OF ELECTROREDUCTIONS .2. GEMINAL DIHALOCYCLOPROPANES [J].

ERICKSON, RE ;

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[6]

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[7]

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[8]

ZUBRITSKII LM, 1987, HOMOGENEOUS CATALYTI

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