AN OCTAHEDRAL-TETRAHEDRAL VANADIUM PHOSPHATE ONE-DIMENSIONAL CHAIN INCORPORATING 1-AMINOETHANE-2-AMMONIUM CATIONS AS LIGANDS

被引：42

作者：

KHAN, MI

HAUSHALTER, RC

OCONNOR, CJ

TAO, CH

ZUBIETA, J

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

[2] UNIV NEW ORLEANS,DEPT CHEM,NEW ORLEANS,LA 70148

来源：

CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 04期

关键词：

D O I：

10.1021/cm00052a001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrothermal reaction of KVO3, C6H5PO3H2, H3PO4, ethylenediamine, (C2H5)(2)NH2Cl, and H2O yields the unusual V-O-P phase VO(PO4)(H2-NCH2CH2NH3) , a material exhibiting a 1D ribbon structure constructed from V(IV) octahedra and PO43- tetrahedra. The H2NCH2CH2NH3+ group serves both as a monodentate ligand through the amine termines and as the cation.

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页码：593 / 595

页数：3

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