A CONDUCTING THALLIUM SALT OF 2,5-DIMETHYL-N,N'-DICYANOQUINONE-DIIMINE, [2,5-DME-DCNQI]2TL - COMPARISON WITH OTHER RELATED RADICAL-ANION SALTS

被引:22
作者
HUNIG, S
MEIXNER, H
METZENTHIN, T
LANGOHR, U
VONSCHUTZ, JU
WOLF, HC
TILLMANNS, E
机构
[1] Institut für Organische Chemie der, Universität Würzburg am Hubland, Würzburg
[2] Physikalisches Institut, Universität, Stuttgart, Stuttgart, D-7000
[3] Mineralogisches Institut, Universität Würzburg, Würzburg
关键词
D O I
10.1002/adma.19900020805
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A radical anion salt based on thallium (see figure, where M = Tl) has been prepared. It is found to be the only such conducting compound, except the copper analogue, which shows a positive NMR knight shift indicating an electronic interaction between the central atom and the ligand. (Figure Presented.) Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:361 / 363
页数:3
相关论文
共 24 条
[1]  
Aumuller A., Hunig S., One-Step Entry toN-Cyanimines and toN,N?-Dicyanoquinonediimines, a Novel Class of Electron-Acceptors, Angewandte Chemie International Edition in English, 23, (1984)
[2]  
Angew. Chem. Int. Ed. Engl., 23, (1984)
[3]  
Liebigs. Ann. Chem., 142, pp. 165-176, (1986)
[4]  
Aumuller A., Hadicke E., Hunig S., Schatzle A., von Schutz J.U., Crystal Structure and Conductivity of a Novel Charge-Transfer Complex ofN,N?-Dicyano-1,4-naphthoquinonediimine and Tetrathiafulvalene, Angewandte Chemie International Edition in English, 23, (1984)
[5]  
Angew. Chem., 96, (1984)
[6]  
Aumuller A., Erk P., Hunig S., Meixner H., von Schutz J.U., Werner H.-P., pp. 997-1006, (1987)
[7]  
Aumuller A., Erk P., Hunig S., von Schutz J.U., Werner H.-P., Wolf H.C., Klebe G., A New Class of Compounds with High Electrical Conductivity, Molecular Crystals and Liquid Crystals, 156, pp. 215-221, (1988)
[8]  
Hunig S., Aumuller A., Erk P., Meixner H., von Schutz J.U., Gross H.-J., Langohr U., Werner H.-P., Wolf H.C., Burschka C., Klebe G., Peters K., von Schnering H.-G., Synthesis and structure of new anion radical salts from DCNQIs, Synthetic Metals, 27, (1988)
[9]  
Werner H.-P., von Schutz J.U., Wolf H.C., Kremer R., Gehrke M., Aumuller A., Erk P., Hunig S., Solid State Commun., 65, pp. 809-813, (1988)
[10]  
Kato R., Kobayashi H., Kobayashi A., Mori T., Inokuchi H., Synth. Met., 27, (1988)