[K([18]CROWN-6)](+)[MO-4(MU(4)-H)(OCH(2)TBU)(12)](-), THE FIRST ALKOXIDOHYDRIDO CLUSTER OF MOLYBDENUM, EVIDENCE FOR A RARE, IF NOT THE FIRST, EXAMPLE OF A MU(4)-HYDRIDE

被引：19

作者：

BUDZICHOWSKI, TA

CHISHOLM, MH

HUFFMAN, JC

EISENSTEIN, O

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

[2] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

[3] UNIV PARIS 11,CHIM THEOR LAB,F-91405 ORSAY,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 02期

关键词：

D O I：

10.1002/anie.199401911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Mo4 butterfly cluster in which a hydrido ligand is bonded to all four metal atoms probably occurs in the anion of the title complex. This anion is accessible from [Mo2(OCH2tBu)6] and K[BsBu3H] in the presence of [18]crown‐6. As shown schematically below the H‐ligand serves to couple two Mo  Mo units to generate the Mo4(μ4‐H)‐containing anion. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：191 / 193

页数：3

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