Alternating olefin/carbon monoxide polymers: A new family of thermoplastics

被引:27
作者
Ash, CE
机构
[1] Venture Development Thermoplastics Westhollow Technology Center, Shell Development Company, Houston
关键词
olefin carbon monoxide polymers; alternating ethylene carbon monoxide copolymers; catalysts; synthesis; thermoplastics; properties; applications;
D O I
10.1080/00914039508031458
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Significant technological advances by Shell over the past decade have led to the development of a new family of thermoplastics. These new materials are perfectly alternating olefin/carbon monoxide polymers which provide a superior combined balance of performance properties not found in other commercial materials. Shell will market these new polymers under the trade mark CARILON(R) Polymers. CARILON(R) polymers are semicrystalline thermoplastics derived from simple and abundant raw materials of carbon monoxide and ethylene (or other alpha-olefins.) These new materials have resulted, in part, from a high activity catalyst invention which enables the polymer to be produced with perfectly alternating units of CO and olefin. The excellent physical, chemical, and barrier properties of these aliphatic polyketone polymers places them in the broad class of materials known as ''engineering thermoplastics'' which are widely used in industrial, automotive, appliance, and electrical applications.
引用
收藏
页码:1 / 13
页数:13
相关论文
共 27 条
[1]  
BALLAUF F, 1971, Patent No. 863711
[2]   PHOTODEGRADABLE POLYETHYLENE [J].
BREMER, WP .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 1982, 18 (02) :137-148
[3]  
BRUBAKER MM, 1950, Patent No. 2495486
[4]   CRYSTAL STRUCTURE OF POLYKETONE (1-1,ETHYLENE-CARBON MONOXIDE COPOLYMER) [J].
CHATANI, Y ;
TAKIZAWA, T ;
MURAHASHI, S ;
NISHIMURA, Y ;
SAKATA, Y .
JOURNAL OF POLYMER SCIENCE, 1961, 55 (162) :811-&
[5]   CO60 GAMMA-RADIATION-INDUCED COPOLYMERIZATION OF ETHYLENE AND CARBON MONOXIDE [J].
COLOMBO, P ;
KUKACKA, LE ;
FONTANA, J ;
CHAPMAN, RN ;
STEINBER.M .
JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1966, 4 (1PA1) :29-&
[6]   EFFICIENT PALLADIUM CATALYSTS FOR THE COPOLYMERIZATION OF CARBON-MONOXIDE WITH OLEFINS TO PRODUCE PERFECTLY ALTERNATING POLYKETONES [J].
DRENT, E ;
VANBROEKHOVEN, JAM ;
DOYLE, MJ .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 417 (1-2) :235-251
[7]  
Drent E., 1984, [No title captured], Patent No. 121965
[8]  
Drent E., 1989, US Patent, Patent No. 4835250
[9]  
Fenton D. M., 1978, US Patent, Patent No. [4 076 911, 4076911]
[10]  
Fenton D. M., 1970, US Patent, Patent No. [3 530 109, 3530109]