PHOTOINDUCED ELECTRON-TRANSFER IN RUTHENIUM-MODIFIED CYTOCHROME-C

被引：23

作者：

GRAY, HB

WINKLER, JR

机构：

[1] Beckman Institute, California Institute of Technology, Pasadena

来源：

PURE AND APPLIED CHEMISTRY | 1992年 / 64卷 / 09期

关键词：

D O I：

10.1351/pac199264091257

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Distant heme-Ru electronic couplings have been extracted from intramolecular electron-transfer rates in Ru(histidine-X) (X=33,39,62) derivatives of cytochrome c. The rates (and the couplings) correlate with the lengths of sigma-tunneling pathways comprised of covalent bonds, hydrogen bonds, and through-space jumps from the histidines to the heme group.

引用

页码：1257 / 1262

页数：6

共 49 条

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