EXTRACTION OF METALLIC CATIONS BY ANODICALLY FORMED POLYDIBENZO-18-CROWN-6 FROM AQUEOUS-SOLUTIONS - A KEY STEP IN THE FORMATION OF METAL POLYMER MATERIALS USED AS ELECTRODE MODIFIERS FOR ELECTROCATALYSIS

被引：7

作者：

ANGELY, L ^{[1
]}

RAULTBERTHELOT, J ^{[1
]}

PESLERBE, G ^{[1
]}

机构：

[1] CNRS,CHIM SOLIDE & INORGAN MOLEC LAB,URA 254,F-35042 RENNES,FRANCE

来源：

SYNTHETIC METALS | 1992年 / 52卷 / 03期

关键词：

D O I：

10.1016/0379-6779(92)90027-G

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The insertion of metallic particles (Pd, Pt, Ir, Rh, Au or Ag) in conductive poly-crown-ether polymers such as poly-dibenzo-18-crown-6 (poly-DB18-C6, a polymer synthesized by anodic means) is described. The electrochemical behaviours of the metal-polymer materials are presented and the catalytic activity of the platinum-polymer is tested with regard to hydrogen evolution or formic acid oxidation in acidic solutions. Finally, an X-ray diffraction scattering study depicts the crystallographic patterns of the metal-polymer samples.

引用

页码：273 / 289

页数：17

共 56 条

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