SYNTHESIS AND REACTIVITY OF IMIDAZOLYL-CONTAINING AND BENZIMIDAZOLYL-CONTAINING COPPER-COMPLEXES

被引：100

作者：

SORRELL, TN

GARRITY, ML

机构：

[1] Department of Chemistry, The University of North Carolina, Chapel Hill

来源：

INORGANIC CHEMISTRY | 1991年 / 30卷 / 02期

关键词：

D O I：

10.1021/ic00002a014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New polydentate ligands having (2-imidazolylethyl)amino and (2-benzimidazolylethyl)amino groups have been prepared via the imidate esters derived from N-(2-cyanoethyl)benzamides. These chelating ligands form stable copper(I) complexes that react with dioxygen at low temperature to give adducts presumed to be dinuclear peroxo complexes on the basis of the similarity of their electronic spectra with those for analogous pyridine-ligated species. A Schiff-base ligand derived from isophthalaldehyde and (aminoethyl)imidazole is hydroxylated when its copper(I) derivative is treated with dioxygen.

引用

页码：210 / 215

页数：6

共 27 条

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