EQUILIBRIUM SWELLING BEHAVIOR OF DILUTE IONIC HYDROGELS IN ELECTROLYTIC SOLUTIONS

被引:64
作者
BRANNONPEPPAS, L [1 ]
PEPPAS, NA [1 ]
机构
[1] PURDUE UNIV,SCH CHEM ENGN,W LAFAYETTE,IN 47907
基金
美国国家科学基金会;
关键词
HYDROGELS; ANIONIC GELS; SWELLING EQUATION; PH-SENSITIVE HYDROGELS; IONIC STRENGTH;
D O I
10.1016/0168-3659(91)90009-3
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Swelling equations are used to analyze the crosslinked structure of ionic hydrogels in contact with water. The equilibrium swelling ratio or equilibrium polymer volume fraction is shown to be a function of the polymer compatibility (as determined by the chi-1 factor), polymer structural parameters and the ionic nature of the hydrogels. Experimental swelling results for anionic hydrogels such as poly(2-hydroxy ethyl methacrylate-co-methacrylic acid) can be predicted by this model.
引用
收藏
页码:319 / 330
页数:12
相关论文
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