MIXED METAL BASES AS PROMOTERS OF 1,4-ELIMINATIONS

被引：41

作者：

MARGOT, C ^{[1
]}

MATSUDA, H ^{[1
]}

SCHLOSSER, M ^{[1
]}

机构：

[1] UNIV LAUSANNE,INST CHIM ORGAN,RUE DE LA BARRE 2,CH-1005 LAUSANNE,SWITZERLAND

来源：

TETRAHEDRON | 1990年 / 46卷 / 07期

关键词：

D O I：

10.1016/S0040-4020(01)82023-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

When treated with the LIDAKOR mixture, allyl type ethers very readily undergo 1,4-elimination to afford conjugated dienes (3 - 73). In typical cases, the reaction is brought about stereo- and regioselectively (2 and 7, respectively). Under suitable conditions, lithium dimethylamide or even lithium diisopropylamide adds to the dienes generated in situ thus leading to a variety of new allyl amines (5 - 8). © 1990.

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页码：2425 / 2430

页数：6

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