ASYMMETRIC METAL-CATALYZED EPOXIDATION OF ELECTRON-DEFICIENT OLEFINS

被引：49

作者：

BAILEY, M ^{[1
]}

STATON, I ^{[1
]}

ASHTON, PR ^{[1
]}

MARKO, IE ^{[1
]}

OLLIS, WD ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)86103-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The SYN diastereospecific epoxidation of acyclic beta-hydroxyketones (beta-hydroxyacrylates) and cyclic beta-hydroxyketones using titanium and vanadium catalysts is reported. Some initial results on the asymmetric epoxidation of these systems using the Sharpless titanium-tartrate catalyst are also described.

引用

页码：495 / 509

页数：15

共 20 条

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