HYDRIDE ADDITION TO [(ETA-5-INDENYL)FE(CO)3]BF4 - EVIDENCE FOR ETA-3-INDENYL INTERMEDIATES

被引：14

作者：

AHMED, H ^{[1
]}

BROWN, DA ^{[1
]}

FITZPATRICK, NJ ^{[1
]}

GLASS, WK ^{[1
]}

机构：

[1] NATL UNIV IRELAND UNIV COLL DUBLIN, DEPT CHEM, DUBLIN 4, IRELAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 418卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)86356-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Spectroscopic evidence is presented for the formation at low temperatures of the eta-3-indenyl intermediate [(eta-3-C9H7)Fe(CO)3H], prior to formation of the normal hydride, [(eta-5-C9H7)Fe(CO)2H], by reduction of the tricarbonylironindenyl cation with sodium cyanoborohydride in acetone.

引用

页码：C14 / C16

页数：3

共 8 条

[1] HYDRIDE REDUCTION OF [(ETA-5-INDENYL)FE(CO)3]BF4 - EVIDENCE FOR (ETA-5-INDENYL)(CO)2FECHO AND (ETA-5-INDENYL)(CO)2FEH [J].

AHMED, H ;

BROWN, DA ;

FITZPATRICK, NJ ;

GLASS, WK .

INORGANICA CHIMICA ACTA, 1989, 164 (01) :5-6

[2]

BROOKHART M, 1988, PROG INORG CHEM, V36, P1

[3] ELECTRONIC-STRUCTURES AND REACTIVITY OF TRICARBONYLTROPYLIUM METAL-COMPLEXES [J].

BROWN, DA ;

FITZPATRICK, NJ ;

MCGINN, MA ;

TAYLOR, TH .

ORGANOMETALLICS, 1986, 5 (01) :152-157

[4] THE PREDICTION OF NUCLEOPHILIC ATTACKING SITES VIA DETERMINANTS OF ACTIVE FRONTIER AND NEAR-FRONTIER ORBITALS [J].

BROWN, DA ;

FITZPATRICK, NJ ;

MCGINN, MA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 293 (02) :235-248

[5]

BROWN DA, 1984, INORG CHIM ACTA, V89, pL7

[6] CHARACTERIZATION OF A STABLE (ETA-3-INDENYL)IRON METALATE, (ETA-3-C9H7)FE(CO)3- - A ROLE FOR ETA-3-ETA-5 INDENYL LIGAND TAUTOMERIZATION DURING ALKYL CO INSERTION REACTIONS [J].

FORSCHNER, TC ;

CUTLER, AR ;

KULLNIG, RK .

ORGANOMETALLICS, 1987, 6 (04) :889-891

[7] SYNTHESIS AND CHARACTERIZATION OF [(ETA5-C5H5)V(CO)3H]-, A NEW ANIONIC VANADIUM CARBONYL HYDRIDE, AND A STUDY OF ITS REDUCTION REACTION WITH ORGANIC HALIDES - OBSERVATION OF A FREE-RADICAL CHAIN PROCESS HAVING AN EXTREMELY RAPID METAL-TO-CARBON HYDROGEN TRANSFER STEP [J].

KINNEY, RJ ;

JONES, WD ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (02) :635-637

[8] REACTION OF HYDRIDE WITH (ETA-5-C9H7)RE(CO)3 - FACILE FORMATION OF [H6RE4(CO)12(2-)] AND INDENIDE [J].

LEE, SW ;

RICHMOND, MG .

INORGANIC CHEMISTRY, 1991, 30 (09) :2237-2239

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