ELECTROKINETICS OF THE SILICA SOLUTION INTERFACE - A FLAT-PLATE STREAMING POTENTIAL STUDY

被引：316

作者：

SCALES, PJ ^{[1
]}

GRIESER, F ^{[1
]}

HEALY, TW ^{[1
]}

WHITE, LR ^{[1
]}

CHAN, DYC ^{[1
]}

机构：

[1] UNIV MELBOURNE, DEPT MATH, PARKVILLE, VIC 3052, AUSTRALIA

来源：

LANGMUIR | 1992年 / 8卷 / 03期

关键词：

D O I：

10.1021/la00039a037

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Details for the construction of a flat plate streaming potential apparatus are presented. Measurements using this apparatus on fused silica slides are reported and analyzed on the basis of a Gouy-Chapman-Stern-Grahame (GCSG) model for the electrical double layer at the silica-aqueous solution interface. It is found that the GCSG model can only partly account for the experimental results. Possible reasons for the discrepancy between experiment and theory are discussed.

引用

页码：965 / 974

页数：10

共 46 条

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