AZACARBONYLATIONS AND OXACARBONYLATIONS OF ALLYL PHOSPHATES CATALYZED BY RHODIUM CARBONYL CLUSTER - SELECTIVE SYNTHESIS OF BETA,GAMMA-UNSATURATED AMIDES, ESTERS, AND ACIDS

被引：18

作者：

IMADA, Y ^{[1
]}

SHIBATA, O ^{[1
]}

MURAHASHI, SI ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 451卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83025-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rhodium-catalyzed carbonylation of allyl phosphates under CO (20 atm) at 50-degrees-C proceeds very efficiently in the presence of amines, alcohols, and water to give the corresponding beta,gamma-unsaturated amides, esters, and acids, respectively. These carbonylations occur with high regioselectivity at the less substituted carbon of allyl unit to give linear beta,gamma-unsaturated acid derivatives.

引用

页码：183 / 194

页数：12

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