AN IRIDIUM COMPLEX OF TRIS(2,4,6-TRIMETHOXYPHENYL)PHOSPHINE

被引:5
作者
BEDFORD, RB
CHALONER, PA
HITCHCOCK, PB
ALJUAID, SS
机构
关键词
D O I
10.1107/S0108270193009424
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure determination of (eta4-1,5-cycloocta-diene)(pyridine)[tris(2,4,6-trimethoxyphenyl)phos-phine]iridium(I) hexafluorophosphate, [Ir(C27H33-O9P)(C8H12)(C5H5N)][PF6] revealed approximate square-pyramidal geometry at the Ir atom with one of the methoxy groups of the phosphine ligand being weakly bound in the apical position [Ir...O = 2.857 (4) angstrom].
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页码:356 / 358
页数:3
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