AN IRIDIUM COMPLEX OF TRIS(2,4,6-TRIMETHOXYPHENYL)PHOSPHINE

被引：5

作者：

BEDFORD, RB

CHALONER, PA

HITCHCOCK, PB

ALJUAID, SS

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193009424

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure determination of (eta4-1,5-cycloocta-diene)(pyridine)[tris(2,4,6-trimethoxyphenyl)phos-phine]iridium(I) hexafluorophosphate, [Ir(C27H33-O9P)(C8H12)(C5H5N)][PF6] revealed approximate square-pyramidal geometry at the Ir atom with one of the methoxy groups of the phosphine ligand being weakly bound in the apical position [Ir...O = 2.857 (4) angstrom].

引用

页码：356 / 358

页数：3

共 18 条

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