HEXADECANUCLEAR POLYOLATOMETALATE OF COPPER(II) IONS AND MULTIDEPROTONATED D-SORBITOL

被引：26

作者：

KLUFERS, P

SCHUHMACHER, J

机构：

[1] Institut Für Anorganische Chemie, Universität Karlsruhe, D‐76128, Engesserstrasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 19期

关键词：

ALKOXO CLUSTERS; COPPER COMPOUNDS; POLYOLATO COMPOUNDS; D-SORBITOL; SUPEREXCHANGE;

D O I：

10.1002/anie.199521191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unsymmetrical, multiply bridging ligands are suitable building blocks for the construction of large ligand–metal frameworks. The nonpolymeric copper(II) complex 1 containing the most copper centers to date was obtained with D‐sorbitol. It contains sixfold and fourfold deprotonated sorbitol. The copper atoms form four groups, within which the atoms are antiferromagnetically coupled even at room temperature. (Formula Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2119 / 2121

页数：3

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