SAMARIUM(II) DIIODIDE-MEDIATED INTERMOLECULAR ALDOL-TYPE REACTION OF PHENACYL BROMIDES WITH CARBONYL-COMPOUNDS

被引：23

作者：

AOYAGI, Y

YOSHIMURA, M

TSUDA, M

TSUCHIBUCHI, T

KAWAMATA, S

TATENO, H

ASANO, K

NAKAMURA, H

OBOKATA, M

OHTA, A

KODAMA, Y

机构：

[1] TOKYO COLL PHARM,HACHIOJI,TOKYO 19203,JAPAN

[2] MEIJI SEIKA KAISHA LTD,KOHOKU KU,YOKOHAMA,KANAGAWA 222,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 06期

关键词：

D O I：

10.1039/p19950000689

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intermolecular aldol type reactions of phenacyl bromides with various carbonyl compounds mediated by samarium(II) diiodide afford beta-hydroxy ketones in moderate to good yields. The addition of N,N,N',N'-tetramethylethylenediamine or diethylaluminium chloride resulted in better yields in some reactions.

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页码：689 / 692

页数：4

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