PHOTODISSOCIATION KINETICS OF THE PARA-NITROTOLUENE MOLECULAR ION ON A NANOSECOND TIME SCALE

被引：35

作者：

CHOE, JC ^{[1
]}

KIM, MS ^{[1
]}

机构：

[1] SEOUL NATL UNIV,DEPT CHEM,SEOUL 151742,SOUTH KOREA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 01期

关键词：

D O I：

10.1021/j100154a014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An experimental method has been developed to study photodissociation kinetics for polyatomic ions on a nanosecond time scale. Details of the method are described. The method has been applied to the photodissociation of the p-nitrotoluene molecular ion. Experimental rate constants were in good agreement with the Rice-Ramsperger-Kassel-Marcus (RRKM) calculation. Kinetic energy release of the photodissociation was also investigated. The experimental kinetic energy release distribution could be well explained by phase space theory.

引用

页码：50 / 56

页数：7

共 51 条

[1] LOW-ENERGY MASS-SPECTRA OF SOME ALIPHATIC-KETONES [J].