SYNTHESIS AND CHARACTERIZATION OF A CATALYTICALLY ACTIVE NICKEL SILICOALUMINOPHOSPHATE CATALYST FOR THE CONVERSION OF METHANOL TO ETHENE

被引:59
作者
THOMAS, JM
XU, Y
CATLOW, CRA
COUVES, JW
机构
[1] Davy Faraday Research Laboratories, Royal Institution, London, W1X 4BS
关键词
D O I
10.1021/cm00016a020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
X-ray absorption (near-edge and extended fine structure) along with diffuse reflectance infrared spectroscopy and other techniques are used to characterize specially prepared crystalline powdered samples of the title catalyst, which is based on the chabazite framework. It is established that the nickel ions that are all in tetrahedral, framework sites (first shell Ni-O distance lying close to 1.98 angstrom), and the loosely bound extraframework protons are thought to be the key components of the catalyst for the highly selective conversion of methanol to ethene.
引用
收藏
页码:667 / 672
页数:6
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