THE PAGODANE ROUTE TO DODECAHEDRANES - AN EFFICIENT VARIANT - NEW SUBSTITUTION PATTERNS

被引：20

作者：

PINKOS, R ^{[1
]}

MELDER, JP ^{[1
]}

PRINZBACH, H ^{[1
]}

机构：

[1] UNIV FREIBURG,INST ORGAN CHEM & BIOCHEM,CHEM LAB,ALBERTSTR 21,W-7800 FREIBURG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 01期

关键词：

D O I：

10.1002/anie.199000921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pagodane → dodecahedrane concept is extended significantly by the SN2 synthetic variant, both from the preparative as well as the methodological standpoint. Starting from the pagodane‐bislactone 1, dodecahedranes and homologous dodecahedranes with specific substitution patterns, e.g. 3 (R  CO2CH3), are accessible via the anti,anti,syn,syn‐dibromide esters 2. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：92 / 95

页数：4

共 28 条

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