ADDUCT BETWEEN QUADRICYCLANE AND (ETA-5-CYCLOPENTADIENYL)(1,2-BENZENEDITHIOLATO)COBALT(III) - FORMATION AND STRUCTURE

被引：30

作者：

KAJITANI, M

HATANO, H

FUJITA, T

OKUMACHI, T

NAGAO, H

AKIYAMA, T

SUGIMORI, A

机构：

[1] Department of Chemistry, Faculty of Science and Technology, Sophia University, Chiyoda-ku, Tokyo, 102

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 430卷 / 03期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/0022-328X(92)83277-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of (eta(5)-cyclopentadienyl)(1,2-benzenedithiolato)cobalt(III) (1) in quadricyclane (Q) at 90-degrees-C gives 1:1 adducts of 1 and Q. The main adduct (40% yield) has a unique structure, in which the 5- and 7-positions of norbornene are bonded to Co and S of 1. A mechanism of the formation of the adduct (by the use of deuterium-labeled Q), including a skeletal rearrangement of Q, is proposed.

引用

页码：C64 / C67

页数：4

共 6 条

[1] PHOTOSENSITIZED ISOMERIZATION INVOLVING SATURATED CENTERS [J].