[MO57FE6(NO)(6)O-174(OH)(3)(H2O)(24)](15-) - A HIGHLY SYMMETRICAL GIANT CLUSTER WITH AN UNUSUAL CAVITY AND THE POSSIBILITY OF POSITIONING PARAMAGNETIC CENTERS ON EXTREMELY LARGE CLUSTER SURFACES

被引：76

作者：

MULLER, A

PLASS, W

KRICKEMEYER, E

DILLINGER, S

BOGGE, H

ARMATAGE, A

PROUST, A

BEUGHOLT, C

BERGMANN, U

机构：

[1] Fakultät Für Chemie, Universität Bielefeld, D-33501

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 08期

关键词：

D O I：

10.1002/anie.199408491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three hundred and twenty‐seven atoms with a combined molecular weight of 9250.9 Da make up the title compound, from which, as a cluster of the mesoscopic range, one can expect unusual material properties. A central O33 polyhedron (shown on the right) defines the unusual cavity of this giant cluster and points to interesting host‐guest chemistry. The cluster has been characterized by numerous analytical and spectroscopic methods. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：849 / 851

页数：3

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