KINETICS OF THE REACTIONS BETWEEN ALKYL RADICALS AND MOLECULAR-OXYGEN IN AQUEOUS-SOLUTION

被引：102

作者：

MARCHAJ, A

KELLEY, DG

BAKAC, A

ESPENSON, JH

机构：

[1] IOWA STATE UNIV SCI & TECHNOL, AMES LAB, AMES, IA 50011 USA

[2] IOWA STATE UNIV SCI & TECHNOL, DEPT CHEM, AMES, IA 50011 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 11期

关键词：

D O I：

10.1021/j100164a051

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rate constant for the reaction R. + O2 --> ROO. in aqueous solution was determined for 18 alkyl radicals by laser flash photolysis. The values are all at the diffusion-controlled limit and lie in the range (1.6-4.9) x 10(9) L mol-1 s-1. The radicals studied are primary, substituted primary, secondary, and benzyl radicals.

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页码：4440 / 4441

页数：2

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