SELECTIVE ETHANE AMMOXIDATION TO ACETONITRILE ON ALUMINA-SUPPORTED NIOBIUM ANTIMONY OXIDES

被引：30

作者：

CATANI, R ^{[1
]}

CENTI, G ^{[1
]}

机构：

[1] DEPT IND CHEM & MAT, VIALE RISORGIMENTO 4, I-40136 BOLOGNA, ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 16期

关键词：

D O I：

10.1039/C39910001081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acetonitrile can be synthesized from ethane by heterogeneous catalytic ammoxidation using Nb-Sb mixed oxides supported on alumina; a new type of (amm)oxidation active site on the catalyst, which can lead to a selective insertion of O-N atoms on the double bond of the intermediate ethylene is suggested.

引用

页码：1081 / 1083

页数：3

共 13 条

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