CATALYTIC ACID FLUORIDE SYNTHESIS VIA CARBONYLATION OF ORGANIC BROMIDES IN THE PRESENCE POTASSIUM FLUORIDE

被引：34

作者：

OKANO, T

HARADA, N

KIJI, J

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 06期

关键词：

D O I：

10.1246/bcsj.65.1741

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various aryl bromides were carbonylated under an atmospheric pressure of carbon monoxide in DMF in the presence of potassium fluoride to give aroyl fluorides in excellent yields. The carbonylation was promoted by the addition of phase transfer catalysts, but the contamination with water reduced the selectivity.

引用

页码：1741 / 1743

页数：3

共 8 条

[1]

Drew D., 1972, INORG SYNTH, V13, P52, DOI DOI 10.1002/9780470132449.CH11

[2] THE CHEMISTRY OF SULFUR TETRAFLUORIDE .2. THE FLUORINATION OF ORGANIC CARBONYL COMPOUNDS [J].