STABILIZATION OF CARBENIUM IONS BY AN ALPHA-AZIDO GROUP

被引：18

作者：

HOZ, S

WOLK, JL

机构：

[1] Department of Chemistry, Bar-Ilan University, Ramat-Gan

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 28期

关键词：

D O I：

10.1016/S0040-4039(00)94506-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The ability of the azido group to stabilize an α carbenium ion was calculated to be intermediate between that OH and NH2. The barrier for the decomposition of the title compound into N2 and H2CN+ is 4.6kcal/mol. © 1990.

引用

页码：4085 / 4088

页数：4

共 17 条

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