KETENE ACETAL METALLOCENE COMPLEXES - CRYSTAL-STRUCTURE OF (C5H5)2TI(CL)OC(OCH3)=C(CH3)2

被引：12

作者：

HORTMANN, K ^{[1
]}

DIEBOLD, J ^{[1
]}

BRINTZINGER, HH ^{[1
]}

机构：

[1] UNIV CONSTANCE,FAK CHEM,POSTFACH 5560,W-7750 CONSTANCE,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 445卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80194-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Titanocene and zirconocene ketene acetal derivatives have been prepared by reaction of the respective metallocene dichloride with the lithium enolate of isobutyric acid methyl ester. The crystal structure of (C5H5)2Ti(Cl)OC(OCH3)=C(CH3) is reported.

引用

页码：107 / 109

页数：3

共 6 条

[1] GROUP-TRANSFER POLYMERIZATION USING CATIONIC ZIRCONOCENE COMPOUNDS [J].

COLLINS, S ;

WARD, DG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) :5460-5462

[2]

Colvin E. W., 1981, SILICON ORGANIC SYNT

[3] SIMPLE SYNTHESIS OF ENOLATE COMPLEXES OF TITANOCENE AND ZIRCONOCENE - MOLECULAR-STRUCTURE OF CP2TI(OC2H3)2 [J].

CURTIS, MD ;

THANEDAR, S ;

BUTLER, WM .

ORGANOMETALLICS, 1984, 3 (12) :1855-1859

[4] SELECTIVE REACTIONS OF ORGANOTITANIUM REAGENTS [J].

REETZ, MT .

PURE AND APPLIED CHEMISTRY, 1985, 57 (12) :1781-1788

[5]

Riediker M., 1989, ANGEW CHEM, V101, P488

[6] GROUP-TRANSFER POLYMERIZATION .1. A NEW CONCEPT FOR ADDITION POLYMERIZATION WITH ORGANO-SILICON INITIATORS [J].

WEBSTER, OW ;

HERTLER, WR ;

SOGAH, DY ;

FARNHAM, WB ;

RAJANBABU, TV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (17) :5706-5708

← 1 →