INSITU SCANNING-TUNNELING-MICROSCOPY OBSERVATIONS OF THE POTENTIAL-DEPENDENT (1X2) RECONSTRUCTION ON AU(110) IN ACIDIC ELECTROLYTES

被引:75
作者
MAGNUSSEN, OM
WIECHERS, J
BEHM, RJ
机构
[1] Abteilung für Oberflächenchemie und Katalyse, Universität Ulm, D-7900 Ulm
关键词
D O I
10.1016/0039-6028(93)90893-O
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report in situ STM results on the structure of the (1 x 2)-reconstructed Au(110) surface in various acidic electrolytes and on the (1 x 1) <--> (1 x 2) structural transformation. A (1 x 2) missing-row reconstructed phase is found at potentials negative of +0.05 V(SCE), while above +0.25 V the unreconstructed (1 x 1) phase prevails. The phase transition in the intermediate potential range is completely reversible, with both phases coexisting in dynamic equilibrium in varying amounts depending on the potential. The reconstruction proceeds via local nucleation and growth of individual missing- and added-row reconstruction elements leading to a large number of characteristic defects, mainly adatom islands. The similarity in mechanism and potential regime of the structural transformation in three different electrolytes makes specific anion effects unlikely.
引用
收藏
页码:139 / 151
页数:13
相关论文
共 34 条
[1]   AN EASILY OPERABLE SCANNING TUNNELING MICROSCOPE [J].
BESOCKE, K .
SURFACE SCIENCE, 1987, 181 (1-2) :145-153
[2]  
BINNIG G, 1983, SURF SCI, V131, pL379, DOI 10.1016/0039-6028(83)90112-7
[3]   THE EFFECTS OF TRACE ANIONS ON THE VOLTAMMETRY OF SINGLE-CRYSTAL GOLD SURFACES [J].
CAHAN, BD ;
VILLULLAS, HM ;
YEAGER, EB .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 306 (1-2) :213-238
[4]   PREPARATION OF MONO-CRYSTALLINE PT MICROELECTRODES AND ELECTROCHEMICAL STUDY OF THE PLANE SURFACES CUT IN THE DIRECTION OF THE (111) AND (110) PLANES [J].
CLAVILIER, J ;
FAURE, R ;
GUINET, G ;
DURAND, R .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 107 (01) :205-209
[5]   ROLE OF ANION ON THE ELECTROCHEMICAL-BEHAVIOR OF A (111) PLATINUM SURFACE - UNUSUAL SPLITTING OF THE VOLTAMMOGRAM IN THE HYDROGEN REGION [J].
CLAVILIER, J .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 107 (01) :211-216
[6]   NOVEL MECHANISM FOR THE FORMATION OF CHEMISORPTION PHASES - THE (2X1)O-CU(110 ADDED-ROW RECONSTRUCTION [J].
COULMAN, DJ ;
WINTTERLIN, J ;
BEHM, RJ ;
ERTL, G .
PHYSICAL REVIEW LETTERS, 1990, 64 (15) :1761-1764
[7]   EXTERNAL-CHARGE-INDUCED SURFACE RECONSTRUCTION ON AG(110) [J].
FU, CL ;
HO, KM .
PHYSICAL REVIEW LETTERS, 1989, 63 (15) :1617-1620
[8]   ATOMIC RELAXATION AT ORDERED ELECTRODE SURFACES PROBED BY SCANNING TUNNELING MICROSCOPY - AU(111) IN AQUEOUS-SOLUTION COMPARED WITH ULTRAHIGH-VACUUM ENVIRONMENTS [J].
GAO, XP ;
HAMELIN, A ;
WEAVER, MJ .
JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (09) :6993-6996
[9]   POTENTIAL-DEPENDENT RECONSTRUCTION AT ORDERED AU(100)-AQUEOUS INTERFACES AS PROBED BY ATOMIC-RESOLUTION SCANNING TUNNELING MICROSCOPY [J].
GAO, XP ;
HAMELIN, A ;
WEAVER, MJ .
PHYSICAL REVIEW LETTERS, 1991, 67 (05) :618-621
[10]   RECONSTRUCTION AT ORDERED AU(110)-AQUEOUS INTERFACES AS PROBED BY ATOMIC-RESOLUTION SCANNING TUNNELING MICROSCOPY [J].
GAO, XP ;
HAMELIN, A ;
WEAVER, MJ .
PHYSICAL REVIEW B, 1991, 44 (19) :10983-10986