THE NEW SUBNITRIDE NABA3N - AN EXTENSION OF ALKALI-METAL SUBOXIDE CHEMISTRY

被引：74

作者：

RAUCH, PE

SIMON, A ^{[1
]}

机构：

[1] MAX PLANCK INST FESTKORPERFORSCH,HEISENBERGSTR 1,W-7000 STUTTGART 80,GERMANY

[2] HARVARD UNIV,DEPT CHEM,CAMBRIDGE,MA 02138

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 11期

关键词：

D O I：

10.1002/anie.199215191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chains of face-sharing, N-centered, trigonal(~)Ba6 antiprisms (shown here) with Na atoms between the chains is a description of the structure of the title compound. The columns of Ba atoms ([Ba2+]3N3-)3e- centered by N atoms show ionic bonding within, but metallic bonding on the "skin" as well as between the columns and the Na atoms, leading to the overall metallic character of the compound.

引用

页码：1519 / 1521

页数：3

共 25 条

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