SYNTHESIS OF MONONUCLEAR AND OLIGOMERIC RUTHENIUM(II) ACETYLIDES

被引：41

作者：

DAVIES, SJ ^{[1
]}

JOHNSON, BFG ^{[1
]}

LEWIS, J ^{[1
]}

RAITHBY, PR ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 414卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)86109-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes trans-[Ru(PMe3)4(C = CPh)2] and trans-[Ru(PMe3)4(C = CC6H4C6H4C = CSnMe3)2] have been prepared from the reaction between trans-[Ru(PMe3)4Cl2] and an excess of either Me3SnC = CPh or Me3SnC = CRC = CSnMe3 (R = p-C6H4C6H4), respectively. However, if only one equivalent of the latter reagent is used the rod-like polymeric species trans-[-Ru(PMe3)4C = CRC = C-]n can be isolated.

引用

页码：C51 / C53

页数：3

共 6 条

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