A PROCESS LEADING TO THE DOMAIN-STRUCTURE OF ANILINE BLACK (POLYANILINE)

被引：22

作者：

LANGER, JJ

机构：

[1] A. Mickiewicz University, Faculty of Chemistry, Organic Semiconductor Laboratory

来源：

SYNTHETIC METALS | 1990年 / 36卷 / 01期

关键词：

D O I：

10.1016/0379-6779(90)90231-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Proton-diffusion controlled self-oxidation (disproportionation) of the emeraldine form of polyaniline is proposed to explain the mechanism of a process leading to the domain structure of aniline black. The electrical conductivity calculated (5-6 S/cm) using EMT for the model structure considered is very close to values measured experimentally by other research workers (1-5 S/cm). © 1990.

引用

收藏

页码：35 / 40

页数：6

相关论文

共 17 条

[1] POLYANILINE - PROCESSABILITY FROM AQUEOUS-SOLUTIONS AND EFFECT OF WATER-VAPOR ON CONDUCTIVITY [J].

ANGELOPOULOS, M ;

RAY, A ;

MACDIARMID, AG ;

EPSTEIN, AJ .

SYNTHETIC METALS, 1987, 21 (01) :21-30

[2] POLYANILINE - SOLUTIONS, FILMS AND OXIDATION-STATE [J].

ANGELOPOULOS, M ;

ASTURIAS, GE ;

ERMER, SP ;

RAY, A ;

SCHERR, EM ;

MACDIARMID, AG ;

AKHTAR, M ;

KISS, Z ;

EPSTEIN, AJ .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1988, 160 :151-163

[3] Calculation of various physics constants in heterogenous substances I Dielectricity constants and conductivity of mixed bodies from isotropic substances [J].

Bruggeman, DAG .

ANNALEN DER PHYSIK, 1935, 24 (07) :636-664

[4]

Bruggeman DAG, 1935, ANN PHYS-BERLIN, V24, P665

[5] POLYANILINE - PROTONIC ACID DOPING OF THE EMERALDINE FORM TO THE METALLIC REGIME [J].

CHIANG, JC ;

MACDIARMID, AG .

SYNTHETIC METALS, 1986, 13 (1-3) :193-205

[6] INSULATOR-TO-METAL TRANSITION IN POLYANILINE - EFFECT OF PROTONATION IN EMERALDINE [J].

EPSTEIN, AJ ;

GINDER, JM ;

ZUO, F ;

WOO, HS ;

TANNER, DB ;

RICHTER, AF ;

ANGELOPOULOS, M ;

HUANG, WS ;

MACDIARMID, AG .

SYNTHETIC METALS, 1987, 21 (01) :63-70

[7] INSULATOR-TO-METAL TRANSITION IN POLYANILINE [J].

EPSTEIN, AJ ;

GINDER, JM ;

ZUO, F ;

BIGELOW, RW ;

WOO, HS ;

TANNER, DB ;

RICHTER, AF ;

HUANG, WS ;

MACDIARMID, AG .

SYNTHETIC METALS, 1987, 18 (1-3) :303-309

[8] CONDUCTIVITY OF INHOMOGENEOUS MATERIALS - EFFECTIVE-MEDIUM THEORY WITH DIPOLE-DIPOLE INTERACTION [J].

GRANQVIST, CG ;

HUNDERI, O .

PHYSICAL REVIEW B, 1978, 18 (04) :1554-1561

[9]

Green A. G., 1910, J CHEM SOC, V97, P2388

[10] Aniline-black and allied compounds Part II [J].

Green, AG ;

Woodhead, AE .

JOURNAL OF THE CHEMICAL SOCIETY, 1912, 101 :1117-1123