SYNTHESIS OF SIMPLE GRAFT POLY(ISOPRENE-G-STYRENE) BY ANIONIC-POLYMERIZATION

被引：70

作者：

MAYS, JW

机构：

[1] Department of Chemistry, University of Alabama at Birmingham, Birmingham, 35294, AL

来源：

POLYMER BULLETIN | 1990年 / 23卷 / 03期

关键词：

D O I：

10.1007/BF01032437

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of a well-defined near-monodisperse polyisoprene-graft-polystyrene copomymer having a single, centrally located graft site is described. The method utilized to prepare this structure involved capping "living" polystyryllithium anions by reaction with methyltriclorosilanne, followed by addition of a slight stoichiometric excess of polyisoprenyllithium. After linking, the residual polyisoprene arms were removed by fractionation to yield the pure graft copolymer. © 1990 Springer-Verlag.

引用

页码：247 / 250

页数：4

共 6 条

[1] DELACRUZ MO, 1986, MACROMOLECULES, V19, P2501
[2] STAR-BRANCHED POLYMERS .1. SYNTHESIS OF STAR POLYISOPRENES USING OCTACHLOROSILANE AND DODECACHLOROSILANES AS LINKING AGENTS
HADJICHRISTIDIS, N
GUYOT, A
FETTERS, LJ
[J]. MACROMOLECULES, 1978, 11 (04) : 668 - 672
[3] Morton M., 1975, RUBBER CHEM TECHNOL, V48, P359, DOI DOI 10.5254/1.3547458
[4] Morton M, 1983, ANIONIC POLYMERIZATI
[5] PREPARATION OF ASYMMETRIC 3-ARM POLYBUTADIENE AND POLYSTYRENE STARS
PENNISI, RW
FETTERS, LJ
[J]. MACROMOLECULES, 1988, 21 (04) : 1094 - 1099
[6] REMPP P, 1988, ADV POLYM SCI, V86, P146

← 1 →