METALLAOXETENE FORMATION BY COUPLING OF CARBAMOYL AND DIFLUOROCARBENE LIGANDS

被引：14

作者：

ANDERSON, S

HILL, AF

SLAWIN, AMZ

WILLIAMS, DJ

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,S KENSINGTON,LONDON SW7 2AY,ENGLAND

[2] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,CHEM CRYSTALLOG LAB,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 03期

关键词：

D O I：

10.1039/c39930000266

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate

引用

页码：266 / 267

页数：2

共 7 条

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