A MILD OXIDIZING REAGENT FOR ALCOHOLS AND 1,2-DIOLS - O-IODOXYBENZOIC ACID (IBX) IN DMSO

被引：457

作者：

FRIGERIO, M

SANTAGOSTINO, M

机构：

[1] Prassis Istituto di Ricerche Sigma-Tau, Milan, Via Forlanini 1/3

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 43期

关键词：

D O I：

10.1016/0040-4039(94)80038-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

o-Iodoxybenzoic acid (IBX) smoothly oxidizes primary and secondary alcohols to aldehydes and ketones, respectively. 1,2-Diols are converted to alpha-ketols or alpha-diketones without any oxidative cleavage of the glycol C-C bond. IBX oxidations are easily conducted in DMSO solution at room temperature, with yields ranging from good to quantitative.

引用

页码：8019 / 8022

页数：4

共 15 条

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