METAL-INDUCED CONVERSION OF A CLOSED RECEPTOR TO AN OPEN RECEPTOR ON A P-TERT-BUTYLCALIX[4]ARENE DIAMIDE DERIVATIVE - FLUORESCENCE DETECTION OF A MOLECULAR RECOGNITION PROCESS

被引：43

作者：

MURAKAMI, H ^{[1
]}

SHINKAI, S ^{[1
]}

机构：

[1] KYUSHU UNIV,FAC ENGN,DEPT ORGAN SYNTH,FUKUOKA 812,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 20期

关键词：

D O I：

10.1039/c39930001533

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular receptors, which change from a 'closed' form with intramolecular hydrogen bonds to an 'open' form with intermolecular hydrogen bonds with a pteridine guest upon Na+-binding designed on a calix[4]arene platform are described; the conversion process is monitored easily by a fluorescence change in a flavin guest.

引用

页码：1533 / 1535

页数：3

共 16 条

[1] THE CHEMISTRY OF SYNTHETIC RECEPTORS AND FUNCTIONAL GROUP ARRAYS .19. GENERAL EFFECTS OF BINDING-SITE WATER EXCLUSION ON HYDROGEN-BOND BASED MOLECULAR RECOGNITION SYSTEMS - A CLOSED BINDING-SITE IS LESS AFFECTED BY ENVIRONMENTAL-CHANGES THAN AN OPEN SITE [J].

ADRIAN, JC ;

WILCOX, CS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (04) :1398-1403

[2] A NEW METAL SENSORY SYSTEM BASED ON INTRAMOLECULAR FLUORESCENCE QUENCHING ON THE IONOPHORIC CALIX[4]ARENE RING [J].

AOKI, I ;

SAKAKI, T ;

SHINKAI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (09) :730-732

[3] MOLECULAR RECOGNITION .12. MOLECULAR RECOGNITION OF NUCLEOTIDES - CONCURRENT HYDROGEN-BONDING AND ELECTROSTATIC INTERACTIONS IN THE 2-POINT FIXATION OF FLAVIN MONONUCLEOTIDE [J].

AOYAMA, Y ;

MIZOKAMI, K ;

TOI, H .

CHEMISTRY LETTERS, 1990, (04) :651-654

[4] PKA OF CALIXARENES AND ANALOGS IN NONAQUEOUS SOLVENTS [J].

ARAKI, K ;

IWAMOTO, K ;

SHINKAI, S ;

MATSUDA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (12) :3480-3485

[5] MOLECULAR INCLUSION IN FUNCTIONALIZED MACROMOLECULES .15. PARA-TERT-BUTYLCALIX[4]ARENE TETRA-ACETAMIDE - A NEW STRONG RECEPTOR FOR ALKALI CATIONS [J].

ARDUINI, A ;

GHIDINI, E ;

POCHINI, A ;

UNGARO, R ;

ANDREETTI, GD ;

CALESTANI, G ;

UGOZZOLI, F .

JOURNAL OF INCLUSION PHENOMENA, 1988, 6 (02) :119-134

[6] FORMATION OF MOLECULAR-COMPLEXES WITH CALIXARENES AS DETECTED BY INDUCED CIRCULAR-DICHROISM [J].

ARIMURA, T ;

SHINKAI, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (06) :1896-1900

[7] HYDROGEN-BONDING AND MOLECULAR RECOGNITION - SYNTHETIC, COMPLEXATION, AND STRUCTURAL STUDIES ON BARBITURATE BINDING TO AN ARTIFICIAL RECEPTOR [J].

CHANG, SK ;

VANENGEN, D ;

FAN, E ;

HAMILTON, AD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (20) :7640-7645

[8] THE USE OF COCRYSTALLIZATION AS A METHOD OF STUDYING HYDROGEN-BOND PREFERENCES OF 2-AMINOPYRIMIDINE [J].

ETTER, MC ;

ADSMOND, DA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (08) :589-591

[9]

HAMILTON AD, 1991, BIOORG CHEM FRONT, V2, P115

[10] A BISUBSTRATE REACTION TEMPLATE [J].

KELLY, TR ;

ZHAO, C ;

BRIDGER, GJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (10) :3744-3745

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