PHOTOCATALYTIC SPLITTING OF WATER

被引：36

作者：

KATAKIS, DF ^{[1
]}

MITSOPOULOU, C ^{[1
]}

KONSTANTATOS, J ^{[1
]}

VRACHNOU, E ^{[1
]}

FALARAS, P ^{[1
]}

机构：

[1] NCSR DEMOKRITOS,GR-15310 ATHENS,GREECE

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1992年 / 68卷 / 03期

关键词：

D O I：

10.1016/1010-6030(92)85246-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The non-biomimetic splitting of water has been achieved using a single photocatalyst-catalyst (tris-[l-(4-methoxyphenyl-2-phenyl-1,2-ethylenodithiolenic-S,S']tungsten), and a reversible electron acceptor (methylviologen). The average quantum yield (in equivalents) in the effective wavelength range in the visible (400-500 nm) is about 4%. The oxidation and reduction cycles of water are fully coupled, in fact they are integrated, in the sense that they are part of a single cycle, rather than of the separate hypothetical cycles with contact points proposed in the literature.

引用

页码：375 / 388

页数：14

共 26 条

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