LUMINESCENT METALLOMACROCYCLES FROM GOLD(I) AND SILVER(I) COMPLEXES OF 2,7-BIS(DIPHENYLPHOSPHINO)-1,8-NAPHTHYRIDINE(L) AND CRYSTAL-STRUCTURE OF [AU(2)KL(3)][CLO4](3)-CENTER-DOT-CH2CL2-CENTER-DOT-2MEOH-CENTER-DOT-0.5H2O

被引：46

作者：

UANG, RH

CHAN, CK

PENG, SM

CHE, CM

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN

[2] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 22期

关键词：

D O I：

10.1039/c39940002561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and X-ray crystal structure of the [Au(2)KL(3)](3+) [L = 2,7-bis(diphenylphosphino)-1,8-naphthyridine] complex which contains an encapsulated K+ ion is described; both the [Au(2)KL(3)](3+) and [Ag(3)L(3)](3+) complexes are emissive in fluid solution with the latter being a powerful photooxidant.

引用

页码：2561 / 2562

页数：2

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